ELECTRODIC POLYMER MATERIALS BASED IN ANILINE: INFLUENCE OF Ni2+, Co2+, AND Cu2+ IONS ON ITS FORMATION

Behaviour of aniline when voltametrically electropolymerized in the presence of Ni2+, Co2+, and Cu2+ cations has been studies 0.1 mol ·L-1 aniline in the presence of 0.01 mol·L-1 copper(II), nickel(II), and cobalt(II) ions and of three inorganic acids: HCl, HNO3, and H2SO4, was used. Aniline shows t...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	BASÁEZ,LUIS, VANYSEK,PETR, RIVAS,BERNABÉ L.
Lenguaje:	English
Publicado:	Sociedad Chilena de Química 2005
Materias:	Electropolymerization aniline metal ion
Acceso en línea:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000300015
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:scielo:S0717-97072005000300015
record_format	dspace
spelling	oai:scielo:S0717-970720050003000152005-11-23ELECTRODIC POLYMER MATERIALS BASED IN ANILINE: INFLUENCE OF Ni2+, Co2+, AND Cu2+ IONS ON ITS FORMATIONBASÁEZ,LUISVANYSEK,PETRRIVAS,BERNABÉ L. Electropolymerization aniline metal ion Behaviour of aniline when voltametrically electropolymerized in the presence of Ni2+, Co2+, and Cu2+ cations has been studies 0.1 mol ·L-1 aniline in the presence of 0.01 mol·L-1 copper(II), nickel(II), and cobalt(II) ions and of three inorganic acids: HCl, HNO3, and H2SO4, was used. Aniline shows that polymerizes in all strong acids and metal ions selected, the reversibility and clarity of the redox processes in the presence of metal ions, indicate that the most accurate conditions for electrosynthesizing polyaniline (Pani) was CuCl2 in 1.0 M HCl; Ni(NO3)2 in 1.0 M HNO3 and in HNO3 1.0 M Co(NO3)2. In all cases, similar voltamograms were obtained and polymer growing changes according to the metal ion used. For Co(II), is more favorable in the following order: H2SO4 > HCl > HNO3. For Ni(II) is H2SO4 > HCl @ HNO3, and for Cu(II) is H2SO4 > HCl @ HNO3. The aim of this work is to study the effects of metal ions on aniline and their electropolymerization in acid mediainfo:eu-repo/semantics/openAccessSociedad Chilena de QuímicaJournal of the Chilean Chemical Society v.50 n.3 20052005-09-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000300015en10.4067/S0717-97072005000300015
institution	Scielo Chile
collection	Scielo Chile
language	English
topic	Electropolymerization aniline metal ion
spellingShingle	Electropolymerization aniline metal ion BASÁEZ,LUIS VANYSEK,PETR RIVAS,BERNABÉ L. ELECTRODIC POLYMER MATERIALS BASED IN ANILINE: INFLUENCE OF Ni2+, Co2+, AND Cu2+ IONS ON ITS FORMATION
description	Behaviour of aniline when voltametrically electropolymerized in the presence of Ni2+, Co2+, and Cu2+ cations has been studies 0.1 mol ·L-1 aniline in the presence of 0.01 mol·L-1 copper(II), nickel(II), and cobalt(II) ions and of three inorganic acids: HCl, HNO3, and H2SO4, was used. Aniline shows that polymerizes in all strong acids and metal ions selected, the reversibility and clarity of the redox processes in the presence of metal ions, indicate that the most accurate conditions for electrosynthesizing polyaniline (Pani) was CuCl2 in 1.0 M HCl; Ni(NO3)2 in 1.0 M HNO3 and in HNO3 1.0 M Co(NO3)2. In all cases, similar voltamograms were obtained and polymer growing changes according to the metal ion used. For Co(II), is more favorable in the following order: H2SO4 > HCl > HNO3. For Ni(II) is H2SO4 > HCl @ HNO3, and for Cu(II) is H2SO4 > HCl @ HNO3. The aim of this work is to study the effects of metal ions on aniline and their electropolymerization in acid media
author	BASÁEZ,LUIS VANYSEK,PETR RIVAS,BERNABÉ L.
author_facet	BASÁEZ,LUIS VANYSEK,PETR RIVAS,BERNABÉ L.
author_sort	BASÁEZ,LUIS
title	ELECTRODIC POLYMER MATERIALS BASED IN ANILINE: INFLUENCE OF Ni2+, Co2+, AND Cu2+ IONS ON ITS FORMATION
title_short	ELECTRODIC POLYMER MATERIALS BASED IN ANILINE: INFLUENCE OF Ni2+, Co2+, AND Cu2+ IONS ON ITS FORMATION
title_full	ELECTRODIC POLYMER MATERIALS BASED IN ANILINE: INFLUENCE OF Ni2+, Co2+, AND Cu2+ IONS ON ITS FORMATION
title_fullStr	ELECTRODIC POLYMER MATERIALS BASED IN ANILINE: INFLUENCE OF Ni2+, Co2+, AND Cu2+ IONS ON ITS FORMATION
title_full_unstemmed	ELECTRODIC POLYMER MATERIALS BASED IN ANILINE: INFLUENCE OF Ni2+, Co2+, AND Cu2+ IONS ON ITS FORMATION
title_sort	electrodic polymer materials based in aniline: influence of ni2+, co2+, and cu2+ ions on its formation
publisher	Sociedad Chilena de Química
publishDate	2005
url	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072005000300015
work_keys_str_mv	AT basaezluis electrodicpolymermaterialsbasedinanilineinfluenceofni2co2andcu2ionsonitsformation AT vanysekpetr electrodicpolymermaterialsbasedinanilineinfluenceofni2co2andcu2ionsonitsformation AT rivasbernabel electrodicpolymermaterialsbasedinanilineinfluenceofni2co2andcu2ionsonitsformation
_version_	1718445352881750016

ELECTRODIC POLYMER MATERIALS BASED IN ANILINE: INFLUENCE OF Ni2+, Co2+, AND Cu2+ IONS ON ITS FORMATION

Ejemplares similares