ORGANOMETALLIC 1,5-BENZODIAZEPINE AND 1,5-BENZODIAZE PINIUM COMPOUNDS: SYNTHESIS, CHARACTERIZATION, X-RAY DIFFRACTION STRUCTURES AND THEORETICAL INVESTIGATION

ORGANOMETALLIC 1,5-BENZODIAZEPINE AND 1,5-BENZODIAZE PINIUM COMPOUNDS: SYNTHESIS, CHARACTERIZATION, X-RAY DIFFRACTION STRUCTURES AND THEORETICAL INVESTIGATION

The organometallic tridentate ketoamine or enaminone compound, (η5-Cp)Fe(η5-C J H4)-C(=0)-CH=C(Me)-NH-C6H4-o-NH2, undergoes an intramolecular cyclocondensation promoted by Cu(C10(4))2-6H(2)0 (2:1 molar ratio) affording the neutral 2-ferrocenyl-4-methyl-1,5-benzodiazepine, 1. Howeve...

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Autores principales: GALLARDO,CRISTINA, TRUJILLO,ALEXANDER, FUENTEALBA,MAURICIO, VEGA,ANDRES, CARRILLO,DAVID, MANZUR,CAROLINA
Lenguaje:English
Publicado: Sociedad Chilena de Química 2007
Materias:
Organometallic diazepine
organometallic diazepinium
DFT calculations
X-ray structures
ferrocenyl ketoamine
ferrocenyl enaminone
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300017
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