ORGANOMETALLIC 1,5-BENZODIAZEPINE AND 1,5-BENZODIAZE PINIUM COMPOUNDS: SYNTHESIS, CHARACTERIZATION, X-RAY DIFFRACTION STRUCTURES AND THEORETICAL INVESTIGATION

The organometallic tridentate ketoamine or enaminone compound, (η5-Cp)Fe(η5-C J H4)-C(=0)-CH=C(Me)-NH-C6H4-o-NH2, undergoes an intramolecular cyclocondensation promoted by Cu(C10(4))2-6H(2)0 (2:1 molar ratio) affording the neutral 2-ferrocenyl-4-methyl-1,5-benzodiazepine, 1. Howeve...

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Auteurs principaux:	GALLARDO,CRISTINA, TRUJILLO,ALEXANDER, FUENTEALBA,MAURICIO, VEGA,ANDRES, CARRILLO,DAVID, MANZUR,CAROLINA
Langue:	English
Publié:	Sociedad Chilena de Química 2007
Sujets:	Organometallic diazepine organometallic diazepinium DFT calculations X-ray structures ferrocenyl ketoamine ferrocenyl enaminone
Accès en ligne:	http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300017
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ORGANOMETALLIC 1,5-BENZODIAZEPINE AND 1,5-BENZODIAZE PINIUM COMPOUNDS: SYNTHESIS, CHARACTERIZATION, X-RAY DIFFRACTION STRUCTURES AND THEORETICAL INVESTIGATION

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