SILICA SUPPORTED RHODIUM METAL NANOPARTICLES STABILIZED WITH (-)-DIOP. EFFECT OF LIGAND CONCENTRATION AND METAL LOADING ON THE ENANTIOSELECTIVE HYDROGENATION OF KETONES

Supported nanoparticles (NPs) in presence of chiral ligand (L) were synthesized for their use in enantioselective hydrogenation reactions. Catalysts were obtained by chemical reduction from rhodium chloride hydrate, RhCl3x3H2O, in presence of (-)-DIOP ligand ((4R,5R)-4,5-Bis(diphenylphosphino-methyl...

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Autores principales: RUIZ,DORIS, MELLA,CLAUDIO, FIERRO,JOSÉ L.G, REYES,PATRICIO
Lenguaje:English
Publicado: Sociedad Chilena de Química 2012
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000400013
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