SILICA SUPPORTED RHODIUM METAL NANOPARTICLES STABILIZED WITH (-)-DIOP. EFFECT OF LIGAND CONCENTRATION AND METAL LOADING ON THE ENANTIOSELECTIVE HYDROGENATION OF KETONES
Supported nanoparticles (NPs) in presence of chiral ligand (L) were synthesized for their use in enantioselective hydrogenation reactions. Catalysts were obtained by chemical reduction from rhodium chloride hydrate, RhCl3x3H2O, in presence of (-)-DIOP ligand ((4R,5R)-4,5-Bis(diphenylphosphino-methyl...
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| Auteurs principaux: | , , , |
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| Langue: | English |
| Publié: |
Sociedad Chilena de Química
2012
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| Sujets: | |
| Accès en ligne: | http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072012000400013 |
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