KINETICS AND MECHANISM OF OXIDATION OF PENTAERYTHRITOL BY DITELLURATOARGENTATE(III) IN ALKALINE MEDIUM

KINETICS AND MECHANISM OF OXIDATION OF PENTAERYTHRITOL BY DITELLURATOARGENTATE(III) IN ALKALINE MEDIUM

The kinetics of oxidation of pentaerythritol by ditelluratoargentate (III) (DTA) in alkaline liquids has been studied spectrophotometrically in the temperature range of 293.2 K-313.2 K. The reaction rate showed first-order dependence in DTA and fractional order with respect to pentaerythritol. It wa...

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Autores principales: JIN-HUAN,SHAN, CAI-HONG,YIN, GANG,BIAN, YAN-PING,LIU
Lenguaje:English
Publicado: Sociedad Chilena de Química 2013
Materias:
Ditelluratoargentate(III)(DTA)
pentaerythritol
redox reaction
reaction kinetics
mechanism
fractional order
k obs, OH-
H4TeO6(2-)
rate equations
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072013000200011
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