SILICA SUPPORTED THALLIUM (III) NITRATE: AN EFFECTIVE OXIDANT FOR OXIDATION OF ALCOHOLS TO THE CARBONYL COMPOUNDS

Thallium (III) Nitrate Supported on Silica gel was found to be an efficient reagent system for oxidation of primary and secondary alcohols to their corresponding carbonyl compounds under mild conditions. The striking features of our method are: short reaction times, formation of no over oxidation pr...

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Auteurs principaux: MANESH,ABBAS AMINI, NAZARI,TAHEREH
Langue:English
Publié: Sociedad Chilena de Química 2015
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Accès en ligne:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072015000300005
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Résumé:Thallium (III) Nitrate Supported on Silica gel was found to be an efficient reagent system for oxidation of primary and secondary alcohols to their corresponding carbonyl compounds under mild conditions. The striking features of our method are: short reaction times, formation of no over oxidation products due to high selectivity and mild nature of oxidant, easy work-up procedure, high yields and carbon carbon double or triple bond functional group in the alcohol structure does not oxidize to other group.