Influence of plasma treatment on SiO2/Si and Si3N4/Si substrates for large-scale transfer of graphene

Abstract One of the limiting factors of graphene integration into electronic, photonic, or sensing devices is the unavailability of large-scale graphene directly grown on the isolators. Therefore, it is necessary to transfer graphene from the donor growth wafers onto the isolating target wafers. In...

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Autores principales: R. Lukose, M. Lisker, F. Akhtar, M. Fraschke, T. Grabolla, A. Mai, M. Lukosius
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Publicado: Nature Portfolio 2021
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spelling oai:doaj.org-article:437b9e6e890d4f0b9a0094b3ddfb0afe2021-12-02T17:12:25ZInfluence of plasma treatment on SiO2/Si and Si3N4/Si substrates for large-scale transfer of graphene10.1038/s41598-021-92432-42045-2322https://doaj.org/article/437b9e6e890d4f0b9a0094b3ddfb0afe2021-06-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-92432-4https://doaj.org/toc/2045-2322Abstract One of the limiting factors of graphene integration into electronic, photonic, or sensing devices is the unavailability of large-scale graphene directly grown on the isolators. Therefore, it is necessary to transfer graphene from the donor growth wafers onto the isolating target wafers. In the present research, graphene was transferred from the chemical vapor deposited 200 mm Germanium/Silicon (Ge/Si) wafers onto isolating (SiO2/Si and Si3N4/Si) wafers by electrochemical delamination procedure, employing poly(methylmethacrylate) as an intermediate support layer. In order to influence the adhesion properties of graphene, the wettability properties of the target substrates were investigated in this study. To increase the adhesion of the graphene on the isolating surfaces, they were pre-treated with oxygen plasma prior the transfer process of graphene. The wetting contact angle measurements revealed the increase of the hydrophilicity after surface interaction with oxygen plasma, leading to improved adhesion of the graphene on 200 mm target wafers and possible proof-of-concept development of graphene-based devices in standard Si technologies.R. LukoseM. LiskerF. AkhtarM. FraschkeT. GrabollaA. MaiM. LukosiusNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-10 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
R. Lukose
M. Lisker
F. Akhtar
M. Fraschke
T. Grabolla
A. Mai
M. Lukosius
Influence of plasma treatment on SiO2/Si and Si3N4/Si substrates for large-scale transfer of graphene
description Abstract One of the limiting factors of graphene integration into electronic, photonic, or sensing devices is the unavailability of large-scale graphene directly grown on the isolators. Therefore, it is necessary to transfer graphene from the donor growth wafers onto the isolating target wafers. In the present research, graphene was transferred from the chemical vapor deposited 200 mm Germanium/Silicon (Ge/Si) wafers onto isolating (SiO2/Si and Si3N4/Si) wafers by electrochemical delamination procedure, employing poly(methylmethacrylate) as an intermediate support layer. In order to influence the adhesion properties of graphene, the wettability properties of the target substrates were investigated in this study. To increase the adhesion of the graphene on the isolating surfaces, they were pre-treated with oxygen plasma prior the transfer process of graphene. The wetting contact angle measurements revealed the increase of the hydrophilicity after surface interaction with oxygen plasma, leading to improved adhesion of the graphene on 200 mm target wafers and possible proof-of-concept development of graphene-based devices in standard Si technologies.
format article
author R. Lukose
M. Lisker
F. Akhtar
M. Fraschke
T. Grabolla
A. Mai
M. Lukosius
author_facet R. Lukose
M. Lisker
F. Akhtar
M. Fraschke
T. Grabolla
A. Mai
M. Lukosius
author_sort R. Lukose
title Influence of plasma treatment on SiO2/Si and Si3N4/Si substrates for large-scale transfer of graphene
title_short Influence of plasma treatment on SiO2/Si and Si3N4/Si substrates for large-scale transfer of graphene
title_full Influence of plasma treatment on SiO2/Si and Si3N4/Si substrates for large-scale transfer of graphene
title_fullStr Influence of plasma treatment on SiO2/Si and Si3N4/Si substrates for large-scale transfer of graphene
title_full_unstemmed Influence of plasma treatment on SiO2/Si and Si3N4/Si substrates for large-scale transfer of graphene
title_sort influence of plasma treatment on sio2/si and si3n4/si substrates for large-scale transfer of graphene
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/437b9e6e890d4f0b9a0094b3ddfb0afe
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