High Pressure Deuterium Passivation of Charge Trapping Layer for Nonvolatile Memory Applications

In this study, the deuterium passivation effect of silicon nitride (Si<sub>3</sub>N<sub>4</sub>) on data retention characteristics is investigated in a Metal-Nitride-Oxide-Silicon (MNOS) memory device. To focus on trap passivation in Si<sub>3</sub>N<sub>4<...

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Autores principales: Jae-Young Sung, Jun-Kyo Jeong, Woon-San Ko, Jun-Ho Byun, Hi-Deok Lee, Ga-Won Lee
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:9de899bdf1e04bddb3e48ab30e7ddd082021-11-25T18:23:04ZHigh Pressure Deuterium Passivation of Charge Trapping Layer for Nonvolatile Memory Applications10.3390/mi121113162072-666Xhttps://doaj.org/article/9de899bdf1e04bddb3e48ab30e7ddd082021-10-01T00:00:00Zhttps://www.mdpi.com/2072-666X/12/11/1316https://doaj.org/toc/2072-666XIn this study, the deuterium passivation effect of silicon nitride (Si<sub>3</sub>N<sub>4</sub>) on data retention characteristics is investigated in a Metal-Nitride-Oxide-Silicon (MNOS) memory device. To focus on trap passivation in Si<sub>3</sub>N<sub>4</sub> as a charge trapping layer, deuterium (D<sub>2</sub>) high pressure annealing (HPA) was applied after Si<sub>3</sub>N<sub>4</sub> deposition. Flat band voltage shifts (ΔV<sub>FB</sub>) in data retention mode were compared by CV measurement after D<sub>2</sub> HPA, which shows that the memory window decreases but charge loss in retention mode after program is suppressed. Trap energy distribution based on thermal activated retention model is extracted to compare the trap density of Si<sub>3</sub>N<sub>4</sub>. D<sub>2</sub> HPA reduces the amount of trap densities in the band gap range of 1.06–1.18 eV. SIMS profiles are used to analyze the D<sub>2</sub> profile in Si<sub>3</sub>N<sub>4</sub>. The results show that deuterium diffuses into the Si<sub>3</sub>N<sub>4</sub> and exists up to the Si<sub>3</sub>N<sub>4</sub>-SiO<sub>2</sub> interface region during post-annealing process, which seems to lower the trap density and improve the memory reliability.Jae-Young SungJun-Kyo JeongWoon-San KoJun-Ho ByunHi-Deok LeeGa-Won LeeMDPI AGarticledeuterium high pressure annealflash memorysilicon nitrideretentionMechanical engineering and machineryTJ1-1570ENMicromachines, Vol 12, Iss 1316, p 1316 (2021)
institution DOAJ
collection DOAJ
language EN
topic deuterium high pressure anneal
flash memory
silicon nitride
retention
Mechanical engineering and machinery
TJ1-1570
spellingShingle deuterium high pressure anneal
flash memory
silicon nitride
retention
Mechanical engineering and machinery
TJ1-1570
Jae-Young Sung
Jun-Kyo Jeong
Woon-San Ko
Jun-Ho Byun
Hi-Deok Lee
Ga-Won Lee
High Pressure Deuterium Passivation of Charge Trapping Layer for Nonvolatile Memory Applications
description In this study, the deuterium passivation effect of silicon nitride (Si<sub>3</sub>N<sub>4</sub>) on data retention characteristics is investigated in a Metal-Nitride-Oxide-Silicon (MNOS) memory device. To focus on trap passivation in Si<sub>3</sub>N<sub>4</sub> as a charge trapping layer, deuterium (D<sub>2</sub>) high pressure annealing (HPA) was applied after Si<sub>3</sub>N<sub>4</sub> deposition. Flat band voltage shifts (ΔV<sub>FB</sub>) in data retention mode were compared by CV measurement after D<sub>2</sub> HPA, which shows that the memory window decreases but charge loss in retention mode after program is suppressed. Trap energy distribution based on thermal activated retention model is extracted to compare the trap density of Si<sub>3</sub>N<sub>4</sub>. D<sub>2</sub> HPA reduces the amount of trap densities in the band gap range of 1.06–1.18 eV. SIMS profiles are used to analyze the D<sub>2</sub> profile in Si<sub>3</sub>N<sub>4</sub>. The results show that deuterium diffuses into the Si<sub>3</sub>N<sub>4</sub> and exists up to the Si<sub>3</sub>N<sub>4</sub>-SiO<sub>2</sub> interface region during post-annealing process, which seems to lower the trap density and improve the memory reliability.
format article
author Jae-Young Sung
Jun-Kyo Jeong
Woon-San Ko
Jun-Ho Byun
Hi-Deok Lee
Ga-Won Lee
author_facet Jae-Young Sung
Jun-Kyo Jeong
Woon-San Ko
Jun-Ho Byun
Hi-Deok Lee
Ga-Won Lee
author_sort Jae-Young Sung
title High Pressure Deuterium Passivation of Charge Trapping Layer for Nonvolatile Memory Applications
title_short High Pressure Deuterium Passivation of Charge Trapping Layer for Nonvolatile Memory Applications
title_full High Pressure Deuterium Passivation of Charge Trapping Layer for Nonvolatile Memory Applications
title_fullStr High Pressure Deuterium Passivation of Charge Trapping Layer for Nonvolatile Memory Applications
title_full_unstemmed High Pressure Deuterium Passivation of Charge Trapping Layer for Nonvolatile Memory Applications
title_sort high pressure deuterium passivation of charge trapping layer for nonvolatile memory applications
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/9de899bdf1e04bddb3e48ab30e7ddd08
work_keys_str_mv AT jaeyoungsung highpressuredeuteriumpassivationofchargetrappinglayerfornonvolatilememoryapplications
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AT junhobyun highpressuredeuteriumpassivationofchargetrappinglayerfornonvolatilememoryapplications
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