Dichloromethylation of enones by carbon nitride photocatalysis
Long-lived carbon nitride radicals have been used in several photocatalytic reactions. Herein, long-lived potassium poly(heptazine imide) radicals enable synthesis of γ,γ-dichloroketones from enones by addition of CHCl2 moiety, generated from chloroform, to the C=C bond.
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Auteurs principaux: | Stefano Mazzanti, Bogdan Kurpil, Bartholomäus Pieber, Markus Antonietti, Aleksandr Savateev |
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Format: | article |
Langue: | EN |
Publié: |
Nature Portfolio
2020
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Accès en ligne: | https://doaj.org/article/bba4242e28b04ef993afb5dbcfe5cf0b |
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