Suppressing hydrogen peroxide generation to achieve oxygen-insensitivity of a [NiFe] hydrogenase in redox active films
Oxidative degradation impedes practical applications of highly active but fragile catalysts. Here the authors show that combining a protection matrix for O2 reduction and hydrogen peroxide decomposition stabilizes highly O2-sensitive hydrogenase in the harsh oxidative conditions of operating fuel ce...
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Main Authors: | Huaiguang Li, Ute Münchberg, Alaa A. Oughli, Darren Buesen, Wolfgang Lubitz, Erik Freier, Nicolas Plumeré |
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Format: | article |
Language: | EN |
Published: |
Nature Portfolio
2020
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Online Access: | https://doaj.org/article/c8dfcdbecf404d3ca4aae12c40bcbe41 |
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