Thermal Stability of SiBCN Films

Silicon-Boron-Carbon-Nitride (SiBCN) thin films were deposited on Si (100) substrates by ECR-type ion beam sputtering at a substrate temperature of 200 ºC, and thermal stability of SiBCN films were investigated at 600 ºC, 700 ºC and 800 ºC in air. A composed Si-B-...

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Autores principales: Naohiro Hayashi, Junho Choi, Tomohisa Kumagai, Takahisa Kato, Masahiro Kawaguchi, Setsuo Nakao, Masami Ikeyama
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Publicado: Japanese Society of Tribologists 2008
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spelling oai:doaj.org-article:db02dd82ffdf4ee3a37329cc0bc91e4e2021-11-05T09:28:53ZThermal Stability of SiBCN Films1881-219810.2474/trol.3.254https://doaj.org/article/db02dd82ffdf4ee3a37329cc0bc91e4e2008-10-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/trol/3/5/3_5_254/_pdf/-char/enhttps://doaj.org/toc/1881-2198Silicon-Boron-Carbon-Nitride (SiBCN) thin films were deposited on Si (100) substrates by ECR-type ion beam sputtering at a substrate temperature of 200 ºC, and thermal stability of SiBCN films were investigated at 600 ºC, 700 ºC and 800 ºC in air. A composed Si-B-C (Si plate and B4C target) target was used for the film deposition. The composition and chemical bonding structure of the prepared films were investigated by X-ray photoelectron spectroscopy and Fourier transform infrared spectrometer. Si-N bonds increased with increasing silicon content. Surface roughness of SiBCN films decreased with increasing Si content. Hardness of SiBCN films exhibited up to 22 GPa with increasing silicon content. SiBCN films showed no changes in chemical bonds after heating at 600 ºC. Even after heating at 700 ºC, SiBCN films maintained relatively high hardness, whereas hardness of SiBCN films was quietly reduced after heating at 800 ºC. Thermal stability of SiBCN films was improved with increasing Si content.Naohiro HayashiJunho ChoiTomohisa KumagaiTakahisa KatoMasahiro KawaguchiSetsuo NakaoMasami IkeyamaJapanese Society of Tribologistsarticlesilicon-boron-carbon-nitride (sibcn)ecr sputteringthermal stabilityoxidation resistancePhysicsQC1-999Engineering (General). Civil engineering (General)TA1-2040Mechanical engineering and machineryTJ1-1570ChemistryQD1-999ENTribology Online, Vol 3, Iss 5, Pp 254-258 (2008)
institution DOAJ
collection DOAJ
language EN
topic silicon-boron-carbon-nitride (sibcn)
ecr sputtering
thermal stability
oxidation resistance
Physics
QC1-999
Engineering (General). Civil engineering (General)
TA1-2040
Mechanical engineering and machinery
TJ1-1570
Chemistry
QD1-999
spellingShingle silicon-boron-carbon-nitride (sibcn)
ecr sputtering
thermal stability
oxidation resistance
Physics
QC1-999
Engineering (General). Civil engineering (General)
TA1-2040
Mechanical engineering and machinery
TJ1-1570
Chemistry
QD1-999
Naohiro Hayashi
Junho Choi
Tomohisa Kumagai
Takahisa Kato
Masahiro Kawaguchi
Setsuo Nakao
Masami Ikeyama
Thermal Stability of SiBCN Films
description Silicon-Boron-Carbon-Nitride (SiBCN) thin films were deposited on Si (100) substrates by ECR-type ion beam sputtering at a substrate temperature of 200 ºC, and thermal stability of SiBCN films were investigated at 600 ºC, 700 ºC and 800 ºC in air. A composed Si-B-C (Si plate and B4C target) target was used for the film deposition. The composition and chemical bonding structure of the prepared films were investigated by X-ray photoelectron spectroscopy and Fourier transform infrared spectrometer. Si-N bonds increased with increasing silicon content. Surface roughness of SiBCN films decreased with increasing Si content. Hardness of SiBCN films exhibited up to 22 GPa with increasing silicon content. SiBCN films showed no changes in chemical bonds after heating at 600 ºC. Even after heating at 700 ºC, SiBCN films maintained relatively high hardness, whereas hardness of SiBCN films was quietly reduced after heating at 800 ºC. Thermal stability of SiBCN films was improved with increasing Si content.
format article
author Naohiro Hayashi
Junho Choi
Tomohisa Kumagai
Takahisa Kato
Masahiro Kawaguchi
Setsuo Nakao
Masami Ikeyama
author_facet Naohiro Hayashi
Junho Choi
Tomohisa Kumagai
Takahisa Kato
Masahiro Kawaguchi
Setsuo Nakao
Masami Ikeyama
author_sort Naohiro Hayashi
title Thermal Stability of SiBCN Films
title_short Thermal Stability of SiBCN Films
title_full Thermal Stability of SiBCN Films
title_fullStr Thermal Stability of SiBCN Films
title_full_unstemmed Thermal Stability of SiBCN Films
title_sort thermal stability of sibcn films
publisher Japanese Society of Tribologists
publishDate 2008
url https://doaj.org/article/db02dd82ffdf4ee3a37329cc0bc91e4e
work_keys_str_mv AT naohirohayashi thermalstabilityofsibcnfilms
AT junhochoi thermalstabilityofsibcnfilms
AT tomohisakumagai thermalstabilityofsibcnfilms
AT takahisakato thermalstabilityofsibcnfilms
AT masahirokawaguchi thermalstabilityofsibcnfilms
AT setsuonakao thermalstabilityofsibcnfilms
AT masamiikeyama thermalstabilityofsibcnfilms
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